| Item | Standard | Typical Result |
|---|---|---|
| Color (Gardner) | ≤ 5 | 5 |
| Iodine Value (gI/100g) | ≤ 2.5 | 2.3 |
| Hydroxy Value (mgKOH/g) | ≥ 155 | 156.7 |
| Melting Point (℃) | ≥ 75 | 76.2 |
| Water & Volatile (%) | ≤ 1.0 | 0.71 |
| Acid Value (mgKOH/g) | 178 - 187 | 181.1 |
| Saponification Value (mgKOH/g) | 180 - 190 | 187.2 |
| CONCLUSION | PASS | Conforms fully to standard |
12-Hydroxystearic Acid (commonly abbreviated as 12-HSA, CAS 106-14-9, molecular formula C18H36O3) is a high-value hydroxylated saturated fatty acid, usually produced by hydrogenation of castor oil-derived ricinoleic acid, appearing as white flake solid.
With a hydroxyl group on the 12th carbon of the carbon chain, it has unique gelling and thickening properties that ordinary stearic acid does not possess. Its most important application is as the core raw material of lithium-based lubricating grease, which reacts with lithium hydroxide to form lithium soap thickener, endowing grease with excellent mechanical stability, water resistance and high temperature performance. It is also widely used as additive in coatings, inks, cosmetics, PVC processing and wax products, playing the roles of thickening, lubrication, emulsification and structure improvement. With high purity, stable quality and good safety, it is an important high-end fine chemical raw material widely used in industry.
A1: Structurally, 12-HSA has an additional hydroxyl group on the 12th carbon of the carbon chain, which brings unique gelling and thickening properties that ordinary stearic acid does not have. In lubricating grease production, 12-HSA can form a stronger three-dimensional network structure, giving grease much better mechanical stability, colloidal stability and higher dropping point, which cannot be achieved by ordinary stearic acid. Ordinary stearic acid is mainly used as surfactant and release agent, while 12-HSA is more used in high-demand thickening scenarios.
A2: No. According to UN GHS classification criteria, 12-hydroxystearic acid is not classified as a hazardous substance. It has very low acute toxicity (oral LD50 >10000 mg/kg in rats), no corrosiveness and no flammability risk under normal temperature. It is classified as non-dangerous goods in international road, sea and air transportation, and can be transported as ordinary industrial chemicals.
A3: Store in tightly sealed original packaging in a cool, dry and well-ventilated warehouse, keep away from high temperature heat sources and strong oxidants. Avoid direct sunlight and humid environment to prevent product oxidation and moisture absorption. Handle gently during loading and unloading to avoid packaging damage. Operators can wear general dust masks and gloves, and avoid long-term inhalation of dust.
A4: Hydroxy value is one of the core quality indicators of 12-HSA, which reflects the content of hydroxyl groups in the product and directly determines the gelling and thickening ability. The higher the hydroxy value, the stronger the thickening performance, and the less dosage is needed to achieve the same grease consistency. High-quality 12-HSA has a hydroxy value ≥155 mgKOH/g, which can ensure stable thickening effect and reduce formulation cost.
A5: Yes. According to standard MITI aerobic biodegradation test, 12-hydroxystearic acid can reach 93% of theoretical BOD within 4 weeks under activated sludge inoculation, showing good biodegradability. It will not accumulate persistently in the environment, and has good environmental compatibility, which meets the requirements of green and sustainable chemical industry.
A6: In general universal lithium-based grease, the typical dosage of 12-HSA is about 8-12% of the total formula, which is saponified with about 1.2-1.8% lithium hydroxide monohydrate in base oil. The specific dosage should be adjusted according to the target consistency (NLGI grade), base oil type and performance requirements of the grease. For complex lithium grease, the formula will be adjusted with other fatty acids.
| Item | Standard | Typical Result |
|---|---|---|
| Color (Gardner) | ≤ 5 | 5 |
| Iodine Value (gI/100g) | ≤ 2.5 | 2.3 |
| Hydroxy Value (mgKOH/g) | ≥ 155 | 156.7 |
| Melting Point (℃) | ≥ 75 | 76.2 |
| Water & Volatile (%) | ≤ 1.0 | 0.71 |
| Acid Value (mgKOH/g) | 178 - 187 | 181.1 |
| Saponification Value (mgKOH/g) | 180 - 190 | 187.2 |
| CONCLUSION | PASS | Conforms fully to standard |
12-Hydroxystearic Acid (commonly abbreviated as 12-HSA, CAS 106-14-9, molecular formula C18H36O3) is a high-value hydroxylated saturated fatty acid, usually produced by hydrogenation of castor oil-derived ricinoleic acid, appearing as white flake solid.
With a hydroxyl group on the 12th carbon of the carbon chain, it has unique gelling and thickening properties that ordinary stearic acid does not possess. Its most important application is as the core raw material of lithium-based lubricating grease, which reacts with lithium hydroxide to form lithium soap thickener, endowing grease with excellent mechanical stability, water resistance and high temperature performance. It is also widely used as additive in coatings, inks, cosmetics, PVC processing and wax products, playing the roles of thickening, lubrication, emulsification and structure improvement. With high purity, stable quality and good safety, it is an important high-end fine chemical raw material widely used in industry.
A1: Structurally, 12-HSA has an additional hydroxyl group on the 12th carbon of the carbon chain, which brings unique gelling and thickening properties that ordinary stearic acid does not have. In lubricating grease production, 12-HSA can form a stronger three-dimensional network structure, giving grease much better mechanical stability, colloidal stability and higher dropping point, which cannot be achieved by ordinary stearic acid. Ordinary stearic acid is mainly used as surfactant and release agent, while 12-HSA is more used in high-demand thickening scenarios.
A2: No. According to UN GHS classification criteria, 12-hydroxystearic acid is not classified as a hazardous substance. It has very low acute toxicity (oral LD50 >10000 mg/kg in rats), no corrosiveness and no flammability risk under normal temperature. It is classified as non-dangerous goods in international road, sea and air transportation, and can be transported as ordinary industrial chemicals.
A3: Store in tightly sealed original packaging in a cool, dry and well-ventilated warehouse, keep away from high temperature heat sources and strong oxidants. Avoid direct sunlight and humid environment to prevent product oxidation and moisture absorption. Handle gently during loading and unloading to avoid packaging damage. Operators can wear general dust masks and gloves, and avoid long-term inhalation of dust.
A4: Hydroxy value is one of the core quality indicators of 12-HSA, which reflects the content of hydroxyl groups in the product and directly determines the gelling and thickening ability. The higher the hydroxy value, the stronger the thickening performance, and the less dosage is needed to achieve the same grease consistency. High-quality 12-HSA has a hydroxy value ≥155 mgKOH/g, which can ensure stable thickening effect and reduce formulation cost.
A5: Yes. According to standard MITI aerobic biodegradation test, 12-hydroxystearic acid can reach 93% of theoretical BOD within 4 weeks under activated sludge inoculation, showing good biodegradability. It will not accumulate persistently in the environment, and has good environmental compatibility, which meets the requirements of green and sustainable chemical industry.
A6: In general universal lithium-based grease, the typical dosage of 12-HSA is about 8-12% of the total formula, which is saponified with about 1.2-1.8% lithium hydroxide monohydrate in base oil. The specific dosage should be adjusted according to the target consistency (NLGI grade), base oil type and performance requirements of the grease. For complex lithium grease, the formula will be adjusted with other fatty acids.